I once did a blog post on the different Spider-Man costumes worn by Spidey up to 2009. I may have missed a few, but I got most of them. Check out Spider-Man Costumes pt 1. Recently however, more specifically, since Big Time, Peter Parker has gotten a new job at Horizon Labs, giving him time and resources to create new Spider-Man Costumes.
Firstly, we have Spider-Man's invisible costume which he first wore in Amazing Spider-Man 650. Take note that this issue came out somewhere around the same time the remake the Tron Legacy- the movie was released.